If you want CA, buy the oldest cheapest lens you can find!
Shooting through flat glass wont give it, but if you use a cheap close up lens, that would (of course, only good for close ups...)
You could probably fake it in photoshop. Split the image into RGB layers and scale each one slightly differently before combining again.
_________________Canon DSLRs: 7D, 5D2, 1D, 600D, 450D full spectrum, 300D IR mod
Lenses: EF 35/2, 50/1.8, 85/1.8, 135/2+SF, 28-80 V, 70-300L, 100-400L, TS-E 24/3.5L, MP-E 65, EF-S 15-85 IS
3rd party: Zeiss 2/50 makro, Samyang 8mm fisheye, Sigma 150 macro, 120-300 f/2.8 OS, Celestron 1325/13
Tinies: Sony HX9V.